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This coenzyme is essential for various biological functions

Metabolic interaction of folate and related B-vitamins Folate, vitamin B 12 , vitamin B 6 and riboflavin interact by functioning as cofactors within OCM, a network of interrelated cellular pathways essential for numerous biological processes, including the biosynthesis of DNA, amino acid interconversions and methylation reactions (Reference Bailey, Stover and McNulty5)

Additionally, sulfite (an intermediate in hydrogen sulfide metabolism) destroys thiamine, and elevated sulfide may also increase the requirement for thiamine in the brain

It means it removes dirt and oil from the skin, two common causes of discolouration